Oxidation and reduction reactions of organic compounds

Reactions that result in fewer multiple bonds are classed as reductions.
Reaction of an alkene with H2 can be described as either an addition or a reduction reaction.
 
Both alkenes and alkynes are susceptible to reduction with H2.
CH3CH=CH2  CH3CH2CH3

Reactions that result in additional carbon-oxygen bonds are classed as oxidations.
Note that in each of the oxidation reactions below, C-H bonds in reactants have been replaced by C-O bonds in products.
 Rolling your your mouse over each reactant highlights the change that has occurred.

 

aldehyde

The oxidant commonly used in organic chemistry is Cr(+6) in the form of chromic acid (H2CrO4). The chromium-containing product is Cr3+(aq).
 
secondary alcohol


primary alcohol

In order to be susceptible to oxidation, a compound must have a carbon bonded to both O and H.
Thus the products of the reactions above are not susceptible to oxidation.
This means that tertiary alcohols such as shown at the right are unreactive toward simple oxidation.