Reaction with asymmetric alkenes

As shown by the reaction of bromine with propene below, addition reaction products have
  • all atoms of both reactants
  • the same arrangement of carbons as the reactant
  • one fewer site of unsaturation than the reactant
  • single bonds to the parts of the reagent from carbon atoms that were doubly bonded in the reactant

CH3CH=CH2+ Br2 

As shown by the reactions of propene and butene with HCl, addition reactions can give rise to
 
  • a single product if either the alkene or the reagent is symmetrical

    CH3CH=CHCH3 + HCl
     
  • two products if both the alkene and the reagent are asymmetric.

    CH3CH=CH2 + HCl