This module develops a scheme emphasizing several aspects of the chemistry of sulfur, the second Group 16 element.

Sulfur has six valence electrons (3s2 3p4). Some of the important sulfur species are shown below with the oxidation state of sulfur in each.

+6SO3
+4SO2
0S
–2H2S, S2–

Sulflur exists as S2– in its binary compounds with metals such as with Na+ in Na2S.