For a second order reaction:
Differential rate equation:rate =
k[A]
2Integrated rate equationIf a plot of 1/[A] vs. t is linear, the reaction is second order in A, and the slope of the line is
k.
Half life:For a first order reaction:
Differential rate equation:rate =
k[A]
Integrated rate equation:ln[A] = -kt + ln[A]
0If a plot of ln[A] vs. t is linear, the reaction is first order in A, and the slope of the line is -
k.
Half life:If the half-life doesn't depend on concentration, the reaction is first order.