For aA + bB

cC + dD
A, B, C and D are substances.
a, b, c and d are coefficients.
| reaction rate = | –Δ[A] | = | –Δ[B] | = | Δ[C] | = | Δ[D] |
| a × Δt | b × Δt | c × Δt | d× Δt |
Δ[A] is read
change in concentration of A and equals the
final - initial concentrations of A.
As
reaction rates must always be
positive, rate is calculated using the negative of a change in concentration of a reactant.
The
relative rates of appearance and disappearance of
various reactants and products
depends on their
coefficient in the balanced equation. Thus the
reaction rate is calculated by dividing the change in concentration of that substance
by the coefficient associated with that substance
in the balanced equation for the reaction.
The
unit associated with
reaction rate is concentration per unit time.
If concentration is measured in
and time in seconds, rate has the unit
s
–1.