Acidity of oxoacids

The acidity of EOH varies widely with the nature of element E.

In an important group of acids known as oxoacids, have E is a p-block element (S, P, C or halogen) bonded to oxo groups and hydroxyl groups (OH). As shown below, E bonded to an oxo group can be represented either as E=O or as the polarized form +E-O (as in HNO3).

The acidity of -OH in oxoacids is higher than that of -OH in water. Their relative acidity depends on the number of oxo- groups at E.
Weak acids have one oxo group.
Strong acids have more than one oxo group.
 
 
weak acids
one oxo oxygen at element E (C, S or P)
CH3CO2HH2CO3H2SO3H3PO4
ethanoic acidcarbonic acidsulfurous acidphosphoric acid
strong acids
two or more oxo oxygens at E (N, S or Cl)
HNO3H2SO4HClO4
nitric acidsulfuric acidperchloric acid