Highlighting the important ideas

The table format that was used in this activity is very useful in equilibrium calculations. Successful solution of such problems depends on
 
  1. writing the Q expression correctly.
    Remember that solids and pure liquids divided by their standard states are 1. Thus they don't appear in Q expressions.

     
  2. paying careful attention to whether to which of the given data refers to initial pressures and which refers to equilibrium pressures.

     
  3. paying careful attention to the sign and magnitude of the changes that you tabulate.
     
    • The ratio of the changes must be the ratio of the coefficients of these substances in the balanced equation
       
    • Substances formed in the reaction approaching equilibrium are assigned positive changes
       
    • Substances consumed in the reaction approaching equilibrium are assigned negative changes.