Learning objectives


[Zn(NH3)4]2+

[Cr(H2O)6]3+
This  module is concerned with aspects of the structure of coordination complexes, examples of which are given below.  
Examples:  [Zn(NH3)4]2+, [Cr(H2O)6]3+, [CuCl2], [Pt(NH3)2Cl2]

On completion of the module you should be able to

  • describe the nature of the bond between the ligand and the metal (metal ion)
     
  • recognise that. for a species to act as a ligand, it must have a non-bonding electron pair at one atom
     
  • deduce the oxidation number (state) of the central metal from the formula for the complex
     
  • deduce the coordination number at the central metal for complexes 
     
  • deduce the geometry of the complex from the coordination number