Learning objectives

This module is concerned with reaction chemistry involved in the procedure for determining the iron(II) content of a sample by titration with potassium
in acidic solution to give manganese(II) and iron(III) ions.

 

iron(II) sulfate (Fe2+)

potassium
(MnO4)

iron(III) nitrate (Fe3+)

manganese(II) sulfate (Mn2+))


On completion of the module you should be able to
 
  • balance the equation for the reaction of iron(II) ions with
    ions in acidic solution to give Mn2+
     
  • choose an appropriate strong acid for use in acidifying the solution and to justify your choice based on redox properties of these acids
     
  • predict the colour of the solution in the titration flask at various points in the titration and to explain why no additional indicator is required
     
  • predict how the outcome of the reaction is changed if insufficient acid is present and to explain the consequence of this on the titre value