The
solubility of a substance in a particular solvent at a given temperature is the maximum amount that will dissolve in a specified volume of the solvent at that temperature.
For solids dissolving in liquid solvents, solubility usually increases with temperature.
Solubility depends on the
chemical nature of
solute and the
solvent. It is difficult to predict, with certainty, the solubility of a substance in a particular solvent.
However it is possible to make educated guesses based on general guidelines which also give insight into the nature of the dissolving process in terms of the ions, atoms and molecules present in the solute and the solvent.
Pure substances can be broadly classified as ionic, molecular, covalent network or metallic.
 Ionic (NaCl) |  Metallic (Cu) |
Covalent network (SiO2) |  Molecule (CCl4) |
The most common
solutes are either ionic or molecular substances.
The most common
solvents are
molecular substances (H
2O, CCl
4, CH
3CH
2CH
2CH
2CH
2CH
3) that exist as liquids at room temperature.
Solvents can be classified as
polar or
non-polar.
 H2O |  CH3CH2OH |
 CH3CH2CH2CH2CH2CH3 |
Water is a
polar solvent (H
2O).
The charge density map shows that the electron cloud of water has a more negative region and a more positive region.Hexane (CH
3CH
2CH
2CH
2CH
2CH
3 ) and other
hydrocarbon solvents are
non-polar.
The electron density map shows no regions of positive and negative charge.
Small alcohols (CH3OH, CH3CH2OH) may also be used as solvents and are of intermediate polarity.
The polarity due to the OH group is diminished by the presence of the hydrocarbon chain.