Consider the reaction of heptane (C
7H
16) with oxygen to give carbon dioxide and water.
Step 1:The equation must use correct formulae and have the form reactants

products.
C
7H
16 + O
2 
CO
2 + H
2O
Step 2:Count the numbers of each type of atom in reactants in products.
7 C
16 H and
2 O in reactants

1 C
2 H 3 O in products
Step 3: Balance the element that occurs in the fewest formulae by changing the coefficient in one or more of these.
If there is more than one element in this category, choose an element other than oxygen or hydrogen.C
7H
16 + O
2
7CO
2 + H
2O
Step 4: Then balance the one of the other atoms that occurs least often.
H is chosen because it is in one reactant and one product.
C
7H
16 + O
2 
7CO
2 +
8H
2O
7 C and
16 H and
2 O 
7 C and
16 H and
(14+8) O Step 5: Continue by balancing any remaining atoms.
C
7H
16 +
11O
2 
7CO
2 + 8H
2O
7 C and
16 H and
22 O
7 C and
16 H and
(14+8) O