The
maximum number of electrons in a
subshell depends on the
number of orbitals in the subshell.
An
orbital is a region in space where an electron is likely to be found. Each orbital can contain two electrons.
The diagrams below show that
orbitals that are given the label
s are spherical about the nucleus.
orbitals that are given the label
p have the shape of a dumbbell with the nucleus being at the centre.
The three diffierent
p orbitals have the same shape but their orientation in space is different.
| Subshell | Number orbitals | Maximum number electrons | Orbital shape |
| s | 1 | 2 |  |
| p | 3 | 6 |  |
For shells that contain both
p and
s orbitals, the
electrons in p orbitals are of
higher energy than the
electrons in s orbitals.This is because, as the diagrams show, electrons in s orbitals can be at the nucleus (which is in the center of the sphere).
In contrast the region in space occupied by electrons in p-orbitals does not include the nucleus.
It is also important to appreciate that the
different orbitals are all on the same atom so that the
overall electron density is
spherical about the nucleus.