Oxidant and reductant strength

The most stable oxidation state is the most reluctant reactant in a redox reaction.
These are marked with asterisks below. Usually elements occur in these oxidation states in nature.
 
For example sodium occurs as Na(+1) in NaCl, magnesium as Mg(+2) in MgCl2.

Group 1 Li Na K Rb Cs
ns1 +1* +1* +1* +1* +1*
  0 0 0 0 0
           
Group 2 Be Mg Ca Sr Ba
ns2 +2* +2* +2* +2* +2*
  0 0 0 0 0
 
Group 13 B Al Ga In Tl
ns2 np1 +3* +3* +3* +3* +3
B and Al have ill-defined
negative oxidation states
+1 +1*
  0 0 0 0 0

 

Species containing atoms in oxidation states other than the most stable tend in their redox reactions to achieve the most stable state.
Thus oxidant/reductant strength can be correlated in a qualitative way with the position of a particular oxidation state in the hierarchy of oxidation states.
 
  • States below the most stable are good reductants (electron donors) (all Group 1, 2 and 13 elements).
  • States above the most stable are good oxidants (electron acceptors) (Tl3+).
  • The most stable state is a weak oxidant/reductant (Tl+ weak oxidant and weak reductant).