Introduction to redox chemistry for sulfuric acid

Most common ion Reductant
strength
F (fluoride) very weak

moderate
Cl (chloride)
Br (bromide)
I (iodide)
The Group
 elements most commonly exist in their compounds as halides when the oxidation state of the halogen is -1.  Atoms in negative oxidation states can act as electron donors (reductants). The product of reaction of halides with oxidants (electron acceptors) is generally the elemental form of the halogen.

2X + oxidant  X2 + product arising from oxidant

The product arising from the oxidant will have one of its atoms in a more negative oxidation state due to accepting electrons.
Thus if a halogen is the oxidant, the product is the corresponding halide ion.
2I + Cl2  I2 + 2Cl
It is easy to predict the product arising from the oxidant in this case as halogens only have one negative oxidation state (X).

sulfur species Oxidation number(S)
H2SO4, SO3, SO42–, HSO4 +6
SO2 +4
S 0
H2S -2
Concentrated sulfuric acid is another example of an oxidant.  In this case is S(+6) accepts electrons. 

H2SO4 + reductant  product(s) arising from reductant + product(s) arising from oxidant

If the reductant is a halide ion, the product arising from it will be a halogen (X2)
H2SO4 + 2X  X2 + product(s) arising from oxidant

As seen in the table at the right, the product arising from S(+6) in H2SO4 accepting electrons is not so easy to predict because there are several oxidation states of sulfur below +6.  This product could be SO2, S or H2S, but it  most certainly is not SO3, SO42–, or HSO4.