| Most common ion | Reductant strength |
| F– (fluoride) | very weak  moderate |
| Cl– (chloride) |
| Br– (bromide) |
| I– (iodide) |
The Group
elements most commonly exist in their compounds as halides when the oxidation state of the halogen is -1. Atoms in negative oxidation states can act as electron donors (reductants). The product of reaction of halides with oxidants (electron acceptors) is generally the elemental form of the halogen.
2X
– + oxidant

X
2 + product arising from oxidant
The product arising from the oxidant will have one of its atoms in a more negative oxidation state due to accepting electrons.
Thus if a halogen is the oxidant, the product is the corresponding halide ion.
2I
– + Cl
2 
I
2 + 2Cl
–
It is easy to predict the product arising from the oxidant in this case as halogens only have one negative oxidation state (X–). | sulfur species | Oxidation number(S) |
| H2SO4, SO3, SO42–, HSO4– | +6 |
| SO2 | +4 |
| S | 0 |
| H2S | -2 |
Concentrated sulfuric acid is another example of an oxidant. In this case is S(+6) accepts electrons.
H
2SO
4 + reductant

product(s) arising from reductant + product(s) arising from oxidant
If the reductant is a halide ion, the product arising from it will be a halogen (X
2)
H
2SO
4 + 2X
– 
X
2 + product(s) arising from oxidant
As seen in the table at the right, the product arising from S(+6) in H
2SO
4 accepting electrons is not so easy to predict because there are several oxidation states of sulfur below +6. This product could be SO
2, S or H
2S, but it most certainly is not SO
3, SO
42–, or HSO
4–.