Reactivity

Benzene is a nucleophile due to its π electrons, but its reactions are slow relative to those of alkenes with the same electrophile (Br2 for example). Thus reagents for the aromatic electrophilic substitutions shown below are a combination of the source of the electrophile and a catalyst which activates the electrophile.

forming a benzene-carbon bond   forming a benzene-halogen bond
CH3COCl

AlCl3
  Br2

FeBr3
 
CH3Cl

AlCl3
  Cl2

FeCl3
 
 forming a benzene-nitrogen bond   forming a benzene-sulfur bond 
  conc HNO3 

conc H2SO4
      SO3

conc H2SO4