Hybrid atomic orbitals result by linear combination of atomic orbitals of similar energies on the same atom. Hybrid sets having geometries corresponding to known arrangements of electrons about atoms are given below.
| Combination of these atomic orbitals from the second shell | gives these hybrid orbitals | having geometry | and these atomic orbitals remain unhybridized |
one s and one p | two sp | linear | two p |
one s and two p | three sp2 | trigonal planar | one p |
one s and three p | four sp3 | tetrahedral | none |
Hybrid orbitals can
overlap with hybrid orbitals or s orbitals on adjacent atoms to give σ(single) bonds.
accomodate nonbonding electron pairs