Lewis structures are used to represent the distribution of the valence electrons for covalently bonded molecules or ions. The electrons at a particular atom may be all bonding or a mixture of bonding and nonbonding.
In the Lewis structure for H
2O, the electrons at H are all bonding.
The electrons at O are a mixture of bonding and nonbonding.
Drawing Lewis structures involves
firstly, counting the total number of
valence electrons available.
secondly, using as many
electrons as required to join atoms by
single bonds.
thirdly, distributing remaining
electrons as
nonbonding electron pairs.
This involves counting the number of electrons already at (around) an atom to determine if it can accommodate additional electron pairs.
The
number of electrons at an atom in a Lewis structure is the number of
bonding electrons plus the number of
nonbonding electrons. The number of bonding electrons includes those shared with other atoms.
The number of electrons at H in the Lewis structure for H2O is 2.
This is the maximum number for hydrogen.
The number of electrons at O in the Lewis structure for H2O is 8.
Elements in the second row of the periodic table (C, N, O and F) can have a maximum of 8 electrons around them. Eight electrons are referred to as an
octet of electrons.