Attractive forces in solids

Solids have a specified shape because of the attractive forces between the structural units of which they are comprised.  Examples of different types of solids, the various structural units and the attractive forces between them are shown below.
 
Network solid
(giant structure)

Covalent bonds between carbon atoms in diamond
strong attractive force

high melting points
no charged particles can move

no conductivity
Ionic solid

Ionic bonds
between cations and anions
strong attractive force

high melting point
ions can move if solid  melted

conducting as a melt
Molecular solid

Temporary dipoles

(also known as van der Waals forces or London dispersion forces)
between I2 molecules
See image below.
weak attractive force

low melting
no charged particles can move

no conductivity
Metallic solid

Metallic bonds
between cations and a sea of electrons
variable attractive force

range of melting points
electrons can move in solid or liquid
 
good conductivity


Temporary dipole attractive forces are stronger if the electron clouds are larger so that the interaction can occur over a larger surface area.
Roll your mouse over the image below to see how temporary dipoles are created when the electron clouds of molecules approach one another.