The mole is defined as a specific number (6.02 × 10
23) of entities. There is more than one type of
chemical entity.
The
atom is the chemical entity for elements represented by the symbol for the element.
Examples of elments represented by the symbol for the element are He, Cu and C. As shown in the diagrams these substances exist as isolated atoms (He) or infinite lattices (Cu or C) where every atom is equivalent to every other atom.
Many common nonmetallic elements exist as molecules.
Molecules are uncharged entities discrete groups of atoms joined by chemical bonds.
Elemental hydrogen exists as diatomic (two-atom) molecules (represented by H
2). The diagram represents a very small sample of hydrogen gas.

The
number of chemical entities in samples of molecular substances depends on which
entity is
specified.
There are 10 H2 molecules in the sample of hydrogen shown.
There are 20 H atoms (each molecule has 2 atoms joined by a chemical bond).
Amount in moles can be used to describe either the number
of
atoms OR the number of
molecules.
1 mol of elemental hydrogen (H2) has 6.02 × 1023 H2 molecules.
1 H2 molecule has 2 H atoms.
1 mol of elemental hydrogen (H2) has 2.0 mol H atoms.
The
amount in moles of specified
atoms in a
molecular substance is the
number of atoms
times the given
amount in moles.
This can be expressed mathematically using n as the symbol for amount in moles.
amount in moles of H atoms = n(H) = 2 × n(H2) = 2 × amount in moles of H2 molecules