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Halving the volume
doubles the pressure.In 1664 Robert Boyle determined experimentally the effect of changing pressure on the volume of a gas at constant temperature.
Boyle found that if the pressure is increased, the volume of the gas decreases as shown in Curve A. Curve A suggests the mathematical relationship shown below between pressure and volume of a gas.
This mathematical relationship suggests that
a
plot of P against 1/V should be
linear.
Curve B shows that this is true.the
product PV should be
constant for all V. Curve C shows that this is true.
A change in either volume or pressure results in a corresponding opposite change in the other.
If either the new pressure or the new volume is known, the other can be calculated.
P1V1 = P2V2Boyle's work contributed to development of a model of the particle nature of matter. Consider the particle view of a gas shown.