1H NMR spectra have
signals in the range 0 - 12 δ (ppm),
relative to the strong
signal due to the twelve equivalent hydrogens in (CH
3)
4Si (
tetramethylsilane, abbreviated as TMS) at
0 ppm.
The exact position (
chemical shift) of a
signal depends on the
bonding environment of that hydrogen.
As shown above, hydrogens bonded to
saturated carbons (H

) absorb between
0-5 δ.
doubly bonded carbons (H–C=) absorb between
5-12 δ.
Elements or groups that
withdraw electron density from around the hydrogen cause the
1H nucleus to absorb at
higher δ (ppm).
The H signal is at higher ppm if X is more electronegative than carbon or is a doubly-bonded atom.
Compare H–C=C with H–C=O.
Compare H–C–C with H–C–O